Electrostrictive Materials

Background

PMN is classified as a relaxor ferroelectric. Relaxors exhibit very high dielectric constants ( K > 20,000), diffuse ferroelectric-to-paraelectric phase transitions, and electrostrictive strain vs. electric field behavior. Strain varies quadratically with electric field for an electrostrictor rather than linearly as for a piezoelectric. For transducer applications, electrostrictors must operate under a dc bias field to induce piezoelectric behavior. Operation under bias is characterized by field dependent piezoelectric and electromechanical coupling coefficients

In the past, PMN materials used for Sonar applications have suffered from low coupling, high loss, and poor reliability. TRS has developed PMN-PT formulations and processing methods that overcome these limitations.


Electrostrictors at TRS

TRS has developed three electrostrictive PMN-PT materials. These materials, designated PMN-15, PMN-38, and PMN-85, have operating temperature ranges of 0 to 30, 10 to 50, and 75 to 95 °C, respectively. A broad range of electromechanical data including coupling coefficient vs. dc bias field and strain vs. electric field and mechanical prestress have been collected for all three materials. In general, the higher temperature materials have higher coupling coefficients at the temperature of the peak dielectric constant.

Strain vs. Electric Field and Temperature for PMN-15
Strain vs. Electric Field and Temperature for PMN-15

 

Actuators.  

TRS PMN-PTs can be used in high-precision positioning devices since they possess very little creep when compared to standard PZTs. Since PMN-PTs exhibit low strain hysteresis, they can be used in applications that typically employ Type I and Type III PZTs, but with the added benefit of higher strains than achievable using those materials.

Sonar Projectors. 

TRS PMN-PTs have 6 to 10 times the strain energy density of Navy Type III ceramic. TRS PMN-PTs can replace Type III PZTs in high power Sonar projectors, resulting in smaller systems, increased power, and suitability for use in shallow water.
 

 

Strain Energy Density Comparisons

Material
Density
(kg/m3)

(GPa)
Strain @ 5 ± 5 kV/cm
(%)
Energy Density
(J/kg)
Hysteresis
(%-Delta-Strain @ Bias)
Type VI
7850
47
0.086
0.55
0.020
Type II
7700
59
0.062
0.37
0.035
Type I
7600
64
0.045
0.21
0.007
Type III
7600
74
0.023
0.06
~ 0
PMN-15 @ 25°C
7700
89*
0.052
0.40
~ 0
PMN-85 @ 85°C
7700
53*
0.084
0.61
0.018**

*  Average compliance for the driving conditions
** Hysteresis decreases with prestress. Hysteresis for soft PZTs increases with prestress.


The following data sheet is available to download:

Data sheets can be viewed using the free Acrobat® Reader.

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©2007 TRS Technologies, Inc. - The information presented on this site has been carefully checked for accuracy and is believed to be correct and current.
TRS assumes no responsibility for the correctness of this information, nor for damages consequent to its use.
All specifications, tolerances, and the like are subject to change without notice.